Caroline Walker Chaffee was born 1759 in Thompson, Windham County, Connecticut, United States to Joshua Walker (1733-) and died 3 November 1845 East Woodstock, Windham County, Connecticut, United States of unspecified causes. She married Chester Chaffee (1755-1841) 1777 in Woodstock, Windham County, Connecticut.
Children
| Name | Birth | Death | Joined with |
| Cyrel Chaffee (1779-1872) | |||
| Hannah Chaffee (1781-1868) | |||
| Abigail Chaffee (1783-1854) | |||
| John Chaffee (1785-1864) | 30 November 1785 Thompson, Windham County, Connecticut, United States | 1 March 1864 | Lydia Elliott (1794-1857) |
| Alpheus Cady Chaffee (1789-1868) | |||
| Caroline Chaffee (1791-1867) | |||
| Sophia Chaffee (1794-1850) | |||
| Chester Chaffee (1798-1873) | |||
| Mary Ann Chaffee (1800-1871) | |||
| Harriet Chaffee (1804-1804) | |||
Siblings