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Karl Ludwig Joseph Maria Habsburg-Lothringen von Österreich was born 30 July 1833 in Vienna, Austria to Franz Karl von Österreich (1802-1878) and Sophie Friederike Dorothea Wilhelmine von Bayern (1805-1872) and died 19 May 1896 Vienna, Austria of unspecified causes. He married Margarete von Sachsen (1840-1858) 1856 . He married Maria Annunziata di Borbone delle Due Sicilie (1843-1871) 21 October 1862 . He married Maria Teresa de Bragança (1855-1944) 1873 .
Children
| Name | Birth | Death | Joined with |
| Franz Ferdinand von Österreich (1863-1914) | 18 December 1863 Graz, Styria, Austria | 28 June 1914 Sarajevo, Bosnia and Herzegovina | Sophie Chotková von Chotkov und Vojnín (1868-1914) |
| Otto Franz Joseph von Österreich (1865-1904) | |||
| Ferdinand Karl von Österreich (1868-1915) | 27 December 1868 Vienna, Austria | 12 March 1915 Munich, Bavaria, Germany | Bertha Czuber (1879-1979) |
| Margarethe Sophie von Österreich (1870-1902) | 13 May 1870 Artstetten-Pöbring, Melk District, Lower Austria, Austria | 24 August 1902 Gmunden, Gmunden District, Upper Austria, Austria | Albrecht von Württemberg (1865-1939) |
| Name | Birth | Death | Joined with |
| Maria Annunziata von Österreich (1876-1961) | |||
| Elisabeth Amalie von Österreich (1878-1960) | 7 July 1878 Reichenau | 13 March 1960 Liechtenstein | Alois von und zu Liechtenstein (1869-1955) |