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Karl Ludwig Ascania von Anhalt-Bernburg-Schaumburg-Hoym, Prince of Anhalt-Bernburg-Schaumburg-Hoym, was born 16 May 1723 in Schloss Schaumburg, Rhineland-Palatinate, Germany to Viktor I. Amadeus Adolf von Anhalt-Bernburg-Schaumburg-Hoym (1693-1772) and Charlotte Luise von Isenburg-Birstein (1680-1739) and died 20 August 1806 Schloss Schaumburg, Rhineland-Palatinate, Germany of unspecified causes. He married Benjamine Gertrud Kaiser (1729-1787) . He married Amalie Eleonore zu Solms-Braunfels (1734-1811) 12 December 1765 in Braunfels, Hesse, Germany.
Children
| Name | Birth | Death | Joined with |
| Viktoria Hedwig Karoline von Anhalt-Bernburg-Schaumburg-Hoym (1749-1841) | |||
| Name | Birth | Death | Joined with |
| Viktor II. Karl Friedrich von Anhalt-Bernburg-Schaumburg-Hoym (1767-1812) | 2 November 1767 Schloss Schaumburg, Rhineland-Palatinate, Germany | 22 April 1812 Schloss Schaumburg, Rhineland-Palatinate, Germany | Amalie von Nassau-Weilburg (1776-1841) |
| Wilhelm von Anhalt-Bernburg-Schaumburg-Hoym (1771-1799) | |||
| Alexius Klemens von Anhalt-Bernburg-Schaumburg-Hoym (1772-1776) | |||
| Sophie Charlotte von Anhalt-Bernburg-Schaumburg-Hoym (1773-1774) | |||
| Karoline Ulrike von Anhalt-Bernburg-Schaumburg-Hoym (1775-1782) | |||