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Sybil of Barcelona was born on an unknown date to Berengar Raymond I de Barcelona (1005-1035) and Guisla of Lluca (?-?) . She married Henry de Bourgogne (1035-c1074) .
Children
| Name | Birth | Death | Joined with |
| Hugh I de Bourgogne (1057-1093) | 1057 | 29 August 1093 Cluny | |
| Eudes I de Bourgogne (1058-1103) | 1058 | 23 March 1103 | Sybille de Bourgogne (c1065-aft1103) |
| Robert de Bourgogne (1059-1111) | 1059 | 1111 | |
| Helie de Bourgogne (1061-aft1084) | 1061 | 1084 | |
| Beatrice de Bourgogne (1063-c1110) | 1063 | 1110 | Guy III de Vignory (c1055-c1117) |
| Reginald de Bourgogne (1065-1092) | 1065 | 1092 | |
| Henry of Portugal (1066-1112) | 1066 | 1112 | Teresa of León (1080-1130) |