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Wilhelm I. von Württemberg was born 27 September 1781 in Lübben to Friedrich I. von Württemberg (1754-1816) and Auguste Karoline von Braunschweig-Wolfenbüttel (1764-1788) and died 25 June 1864 Schloss Rosenstein of unspecified causes. He married Karoline Charlotte Auguste von Bayern (1792-1873) 8 June 1808 in Munich. He married Ekaterina Pavlovna Romanova (1788-1819) 24 January 1816 . He married Pauline von Württemberg (1800-1873) 15 April 1820 in Stuttgart.
Children
| Name | Birth | Death | Joined with |
| Marie von Württemberg (1816-1887) | |||
| Sophie von Württemberg (1818-1877) | 17 June 1818 Stuttgart | 3 June 1877 The Hague | Willem III van Oranje-Nassau (1817-1890) |
| Name | Birth | Death | Joined with |
| Katharina von Württemberg (1821-1898) | 24 August 1821 Stuttgart | 6 December 1898 Stuttgart | Friedrich von Württemberg (1808-1870) |
| Karl I. von Württemberg (1823-1891) | 6 March 1823 Stuttgart | 6 October 1891 Stuttgart | Olga Nikolaevna of Russia (1822-1892) |
| Auguste von Württemberg (1826-1898) | |||